Fire Suppression and Lithium-Ion Batteries

Originally published February 17, 2022 11:02:44 PM, updated February 17, 2022

With a growing number of batteries in the workplace now being composed of lithium, it’s important to consider the characteristics of the popular lithium-ion battery. It’s also vital to understand how lithium-ion batteries could affect workplace health and safety within your organisation. In this blog, we’ll be looking at lithium-ion batteries and explaining what factors can influence the likelihood and impact of a fire or explosion. We’ll also be highlighting the importance of fire suppression features in your battery charging stores, so you can reduce the spread of a lithium-ion battery fire. But first, let’s get started by detailing the unique way in which a lithium-ion battery operates.

How Does A Lithium-Ion Battery Work?

The safety issues that come with charging a lithium-ion battery occur due to the specific way that the battery works.

Lithium-ion batteries operate differently from other batteries, such as a lead acid battery, due to the lithium ions moving through electrolyte between the positive (cathode) and negative (anode) electrodes.

When the battery is being charged, the current is sent from the charger to the battery which causes lithium ions to move from the cathode to the anode through the electrolyte. This process is reversed when the battery is discharging, and the lithium ions stored within the anode then move through the electrolyte to the cathode.

Compared with a more traditional workplace battery, such as a lead-acid battery, lithium-ion batteries provide superior lifespan, efficiency, performance and energy density. However, the innovative design of a lithium-ion battery is not without safety issues. This kind of battery has been known to overheat, melt, ignite and explode under certain conditions — some of which we’ll detail below.

What Safety Issues Are Associated With Lithium-Ion Battery Charging?

While lithium-ion battery fires and explosions thankfully aren’t a regular occurrence in workplaces, they can (and do) happen in circumstances when the stability of the battery is put at risk.

There are many factors which can affect the safety of a lithium-ion battery.

These include:

  • Ambient temperature– lithium-ion batteries are sensitive to excessive heat, so should be used, stored and charged in the temperature range recommended by the battery manufacturer.
  • The surface the battery is being charged on – you should never charge lithium-ion batteries on a soft or combustible surface, such as a car seat, chair or bed.
  • Ventilation – due to the sensitivity of lithium-ion batteries to humidity and heat, you should only store and charge them in a well-ventilated area
  • The condition of the battery – has the battery been damaged or is it swollen? If your lithium-ion batteries have been damaged they should be disposed of safely.
  • Age of the battery – aged batteries have been known to cause safety hazards, so they should also be discarded if showing signs of disrepair.
  • Manufacturing fault – to avoid using batteries that are intrinsically unsafe, make sure you adhere to any recommendations made by the battery manufacturer in regard to the recall of faulty products.
  • Quality of charging cord – you should follow manufacturer’s instructions and only charge with the original cord or a cord made that meets national safety regulations.
  • Overcharging – avoid overcharging your lithium-ion batteries by monitoring the state of charge.
  • Overdischarging – damage can occur to your lithium-ion battery if it’s left to discharge for long periods of time. Just like you’d monitor for overcharging, you should also be mindful of charging your battery once it’s fully discharged.

If the battery does suffer a short circuit (due to damage, age or manufacturing flaws) or there is an unsafe electrical current (due to overcharging or an electrical fault), it can spark thermal runaway which can lead to a lithium-ion battery fire or explosion.

Thermal Runaway

There are two key considerations to make when caring for your lithium-ion batteries. These are providing a temperature-controlled environment (cool, dry) for storage and charging, and ensuring that charging voltage is regulated.

If these two considerations are not actioned by your organisation, there is a risk that thermal runaway could occur.

A single battery cell can be affected by thermal runaway. However, if you’re storing other lithium-ion batteries nearby, these will also succumb to thermal runaway — and increase the impact of a fire or explosion.

Remember, once the process of thermal runaway has begun in your battery, it can’t be stopped. Thermal runaway can lead to incidents of fire and explosion.

Lithium-Ion Battery Fires

Lithium-ion battery fires can be sparked by a range of issues that could involve the battery itself, the charger, how the battery’s been handled or the environment in which it’s being used or charged.

But what is a lithium-ion battery fire and why is it so dangerous? Let’s first have a look at a real-life example of a devastating battery fire that occurred in 2021 in Australia.

Victorian Big Battery Site Fire, Victoria

A fire broke out at the largest Tesla battery installation in the southern hemisphere at the Victorian Big Battery Site located near Geelong. The lithium battery became engulfed in flames which quickly spread to a nearby battery tank. The lithium battery fire took three days to extinguish and has raised concerns about the safety of lithium batteries for renewable energy storage.

Workplace Fire

Lithium-ion batteries have been responsible for causing many devestating workplace fires across Australia and the globe. 

Why Are Lithium-Ion Battery Fires So Dangerous?

A lithium-ion battery fire is particularly hard to contain — and can therefore put real strain on the emergency services who are attending the site.

As a self-sustaining fire, they are extremely hot and fast burning. They release large amounts of dangerous fumes which are harmful to human health. The batteries can also explode in the fire, which leads to extensive damage both people and the business itself.

Firefighters in Australia currently use water to extinguish lithium-ion battery fires, but the blazes have proven to be extremely destructive and hard to put out. The lithium-ion battery, being so susceptible to heat, will continue to catch alight even after it’s been extinguished by fire crews.

Firebox Australia has developed a LI-ion Fire Solution extinguisher to combat this hazard. As a water type fire extinguisher, with F-500 Encapsulator agent, the extinguisher works to remove heat and halt the reaction of the electrode material and components within the battery. The F-500 agent can penetrate the structure of the battery and successfully extinguish the lithium-ion battery fire.

IMPORTANT: To reduce your risk of lithium-ion battery fires, take a comprehensive approach by investing in battery cabinets and quality chargers, educating staff about risks, developing specific emergency procedures, and providing the correct firefighting equipment for lithium-ion battery fires.

Why Is Fire Suppression Important With Lithium-Ion Battery Stores?

Due to the risk of thermal runaway and lithium-ion battery fires, it’s important that fire suppression is considered when determining your battery charging and storage needs.

If a fire breaks out when your lithium-ion batteries are charging, it’s vital that the fire is contained as much as possible. When a battery cell ignites without a fire suppression system in place (ie. a battery cell left charging on a worker’s desk or multiple batteries left charging in an office), the fire can quickly spread through the workplace.

Lithium-ion battery fires can rapidly engulf buildings and destroy property. They will also spark further thermal runaway in nearby battery stores — causing extreme damage to your organisation, and potentially the surrounding community.

One of the most important features that you should consider for your lithium-ion battery stores is the provision for fire suppression. If a lithium-ion battery fire did break out in your workplace, your battery charging and storage facility should contain the fire so emergency evacuation plans can be actioned.

Fire Suppression In Battery Cabinets

While a fire suppression system will not stop a lithium-ion battery fire, it will contain the blaze for an amount of time which enables your workplace to take action — and save lives.

Fire suppression features in battery cabinets allow organisations to:

  • Evacuate the building
  • Action emergency procedures
  • Use firefighting equipment, if safe to do so
  • Notify fire services

Fire suppression will also assist with containing the fire, so it doesn’t spark further problems when it meets your other lithium-ion battery stores or workplace chemicals.

Battery charging cabinet

Choosing a battery cabinet to charge and store your lithium-ion batteries can reduce the risk of fire.

Battery cabinets with fire suppression may offer design and construction features such as:

  • Non-combustible construction materials
  • Sealed gaps around doors and into spaces between walls
  • A 40mm thermal air barrier between walls
  • Self-closing, close-fitting doors

What Other Features Are Important For Risk Reduction?

While a fire suppression system for your battery charging cabinet will help you reduce the impact of a blaze caused by thermal runaway, there are other features you should consider if you want to prevent battery fires from occurring.

Lithium-ion batteries should be stored in a cool, dry and well-ventilated environment that prevents batteries overheating. Battery cabinets should also be used to decrease the likelihood of impact damage, which can render your batteries unsafe and potentially spark a lithium-ion battery fire. You should also consider a spill containment system in case any damaged lithium-ion batteries leak while they are in storage.

Supressing The Risk Of Lithium-Ion Battery Fires

By choosing to handle, store and charge your batteries in a safe and careful manner, you can reduce the risk of lithium-ion battery fires in your workplace. Charging your batteries with a quality charger, in a temperature-controlled and ventilated environment, is an excellent way of reducing risk. However, in the event of battery fire, it’s essential that your battery cabinet is equipped with a fire suppression system.

If you’d like to learn more about creating a safer work environment in your organisation, we have an eBook that can help. How To Manage The Risk Of Hazardous Chemicals In The Workplace can be applied to any dangerous goods in your organisation – including Class 9 batteries. It explains how you can systematically identify, assess and control and sustain chemical risks such as lithium-ion battery fires. Grab your copy today – it’s completely free and yours to download now.

 

How to manage the risk of hazardous chemicals in the workplace

Walter Ingles

Walter Ingles Compliance Specialist

Walter is STOREMASTA’s Dangerous Goods Storage Specialist. He helps organisations reduce risk and improve efficiencies in the storage and management of dangerous goods and hazardous chemicals.

Like what you’re reading?

Subscribe to stay up to date with the latest from STOREMASTA®


Recommended Resources

Dangerous Goods Segregation Guide
A PRACTICAL EBOOK

How to segregate incompatible classes of dangerous goods

Segregate the 9 different classes of dangerous goods in a way which will reduce risk to people, property, and the environment.

Learn more

Creating an Inspection Checklist for Corrosive Chemical Stores
From the blog

Creating an Inspection Checklist for Corrosive Chemical Stores

Have you just bought a corrosive storage cabinet or installed a chemical storage container outdoors? Then this blog is ...

Learn more

Can Class 8 Acids and Alkalis Be Stored Together?
From the blog

Can Class 8 Acids and Alkalis Be Stored Together?

When you’re carrying any type of corrosives, one of the most common queries is ‘Can Class 8 acids and alkalis be stored ...

Learn more

Challenges Of Storing Dangerous Goods Outdoors
From the blog

Challenges Of Storing Dangerous Goods Outdoors

Are you thinking about storing dangerous goods outdoors? Before you set up your chemical store, there are a few key ...

Learn more

Chemical Spill Response: 5 Mistakes To Avoid
From the blog

Chemical Spill Response: 5 Mistakes To Avoid

Do you feel confident that your staff are completely prepared to effectively manage a successful chemical spill ...

Learn more